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Geoffrey W. Coates

Tisch University Professor

Olin Chemistry Research Wing, Room 560A
gc39@cornell.edu
607-255-5447

Educational Background

PhD, Stanford University, 1994
BA, Wabash College, 1989

Website(s)

Overview

Prof. Coates is the Tisch University Professor in the Department of Chemistry and Chemical Biology at Cornell University. His teaching and research interests involve science at the interface of organic, inorganic, and materials chemistry. The broader impacts of his research include benign polymers and chemical synthesis, the utilization of renewable resources, and materials safe and economical energy storage and conversion.

Keywords

Polymer synthesis, stereoslective catalysis, mechanism of metal catalyzed reactions

Departments/Programs

  • Chemistry and Chemical Biology

Graduate Fields

  • Chemistry and Chemical Biology

Research

The research focus of my group is the development of new synthetic strategies for producing polymers of defined structure. The control of polymer composition, architecture, stereochemistry, and molecular weight allows the indirect control of polymer properties via polymer morphology. Our research projects are interdisciplinary, addressing problems at the interface of organic, inorganic, organometallic, and polymer chemistry.

Courses

Publications

  1. Eagan, J. E.; Xu, J.; Di Girolamo, R.; Thurber, C. M.; Macosko, C. W.; LaPointe, A. M.; Bates, F. S.; Coates, G. W. “Combining Polyethylene and Polypropylene: Enhanced Performance with PE/iPP Multiblock Polymers” Science 2017, 355, 814−816.

  2. DiCiccio, A. M.; Longo, J. M.; Rodríguez-Calero, G. G.; Coates, G. W. “Development of Highly Active and Regioselective Catalysts for the Copolymerization of Epoxides with Cyclic Anhydrides: An Unanticipated Effect of Electronic Variation” J. Am. Chem. Soc. 2016, 138, 7107−7113.

  3. Van Zee, N. J.; Sanford, M. J.; Coates, G. W. “Electronic Effects of Aluminum Salph Complexes in the Copolymerization of Propylene Oxide with Tricyclic Anhydrides: Access to Well-Defined, Functionalizable Aliphatic Polyesters” J. Am. Chem. Soc. 2016, 138, 2755−2761.

  4. Long, B. K.; Eagan, J. M.; Mulzer, M.; Coates, G. W. “Semi-Crystalline Polar Polyethylene: Ester-Functionalized Linear Polyolefins Enabled by a Functional Group Tolerant, Cationic Nickel Catalyst” Angew. Chem. Int. Ed. 2016, 55, 7106−7110.

  5. Zheng, Q.; Ma, L.; Khurana, R.; Archer, L. A.; Coates, G. W. “Structure-Property Study of Cross-Linked Hydrocarbon/Poly(ethylene oxide) Electrolytes with Superior Conductivity and Dendrite Resistance” Chem. Sci. 2016, 7, 6832−6838.

  6. Dunn, E. W.; Lamb, J. L.; LaPointe, A. M.; Coates, G. W. “Carbonylation of Ethylene Oxide to β-Propiolactone: A Facile Route to Poly(3-Hydroxypropionate) and Acrylic Acid” ACS Catalysis, 2016, 6, 8219−8223.

  7. John, A.; Miranda, M. O.; Ding, K.; Dereli, B.; Ortuño, M. A.; LaPointe, A. M.; Coates, G. W.; Cramer, C. J.; Tolman, W. B. “Nickel Catalysts for the Dehydrative Decarbonylation of Carboxylic Acids to Alkenes” Organometallics, 2016, 35, 2391−2400.

  8. Longo, J. M.; Sanford, M. J.; Coates, G. W. “Ring-Opening Copolymerizations of Epoxides and Cyclic Anhydrides with Discrete Metal Complexes: Structure-Property Relationships” Chem. Rev., 2016, 116, 15167−15197.

  9. Lamb, J. R.; Mulzer, M.; LaPointe, A. M.; Coates, G. W. “Regioselective Isomerization of 2,3-Disubstituted Epoxides to Ketones: An Alternative to the Wacker Oxidation of Internal Alkenes” J. Am. Chem. Soc. 2015, 137, 15049−15054.

  10. Cowman, C. D.; Padgett, E.; Tan, K. W.; Hovden, R.; Gu, Y.; Andrejevic, N.; Muller, D.; Coates, G. W.; Wiesner, U. B. “Multicomponent Nanomaterials with Complex Networked Architectures from Orthogonal Degradation and Binary Metal Backfilling in ABC Triblock Terpolymers” J. Am. Chem. Soc. 2015, 137, 6026–6033.